Monthly Archives: September 2024

Fermi’s Golden Rule

Problem: Before developing FGR, it is first necessary to lay out as a prerequisite the general framework of time-dependent perturbation theory (FGR is then a special case thereof). To this effect, consider the usual (Schrodinger picture) Hamiltonian decomposition \(H=H_0+V\), and … Continue reading

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Perturbation Theory and the Stark Effect

The purpose of this post is to provide some examples of perturbation theory calculations in quantum mechanics by analyzing a specific perturbation called the Stark effect. For simplicity, we take as our quantum system a hydrogen atom with the usual … Continue reading

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Motivating the Wigner-Eckart Theorem

Consider the three \(\ell=1\) spherical harmonics: \[Y_{1}^{-1}(\theta,\phi)=\sqrt{\frac{3}{8\pi}}\sin\theta e^{i\phi}\] \[Y_0^0(\theta)=\sqrt{\frac{3}{4\pi}}\cos\theta\] \[Y_{1}^{1}(\theta,\phi)=-\sqrt{\frac{3}{8\pi}}\sin\theta e^{-i\phi}\] Although the spherical harmonics are just functions of \(\theta,\phi\) on the sphere \(S^2\), one can introduce an \(r\)-dependence simply by multiplying each of them by \(r\). The resulting functions … Continue reading

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Relativistic Electrodynamics

Problem: Working on the flat manifold of Minkowski spacetime \(X\cong\mathbf R^{1,3}\) equipped with the Lorentzian metric signature \((+,-,-,-)\), define what is meant by a Lorentz scalar, a Lorentz vector (also called a 4-vector), a Lorentz tensor, and a Lorentz spinor. … Continue reading

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Classical Ideal Gases

Problem: Define an ideal gas (whether that be classical or quantum). Write down the single-particle canonical partition function \(Z_1\) for a classical, monatomic ideal gas, and hence the \(N\)-particle canonical partition function \(Z_N\) in terms of \(Z_1\) (assuming all \(N\) … Continue reading

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Equilibrium Ensembles

The purpose of this post is to lay out the basic theory of ensembles in statistical mechanics in addition to some examples. At the end, the goal will be to convincingly demonstrate ensemble equivalence. Any system (e.g. a gas, a … Continue reading

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Tight-Binding Electrons

Problem: What is the state space \(\mathcal H_{\text{TB}}\) of the tight-binding model on a lattice \(\Lambda\) in \(\mathbf R^d\), ignoring spin degrees of freedom and assuming a single state/”orbital” per lattice point in \(\Lambda\). Solution: The tight-binding model assumes a … Continue reading

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Virial Theorem

Problem: Consider a classical particle subject to Newton’s second law \(\dot{\textbf p}=\textbf F\). If one takes the dot product of both sides with the particle’s velocity \(\dot{\textbf x}\) so that \(\dot{\textbf p}\cdot\dot{\textbf x}=\textbf F\cdot\dot{\textbf x}\), the left hand side is … Continue reading

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Classical vs. Quantum Rutherford Scattering

The purpose of this post is to contrast the classical treatment of Rutherford scattering with its quantum mechanical treatment. At the end, the surprise will be that for certain important quantities such as the differential cross-section, the classical and quantum … Continue reading

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Tinkering

Problem: Mobius transformations (also called fractional linear transformations) are maps \(\mathcal M:\textbf C\cup\{\infty\}\to\textbf C\cup\{\infty\}\) on the Riemann sphere \(\textbf C\cup\{\infty\}\) of the form \(\mathcal M(z):=\frac{az+b}{cz+d}\) for \(\det\begin{pmatrix}a&b\\c&d\end{pmatrix}\neq 0\). The purpose of this problem is to gain a deeper appreciation for … Continue reading

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